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					 Water Saturation From SIGMA and FNXS Logs Logs that come under this designation are the Thermal Decay Time (TDT) or Neutron Lifetime (NLL)  
					Logs. They are also called
                Pulsed Neutron (PNL) or Pulsed Decay Time (PDK) Logs. The 
					primary measurement is the formation capture cross section 
					ISIGMA). Some tools provided a compensated neutron porosity 
					(TPHI) derived from the ratio of the near to far detector 
					count rates.
 
 Newer induced gamma ray spectroscopy tools also provide  
					SIGMA and TPHI, and a recent tool gives a new measurement 
					called fast neutron cross section (FNXS).
 
 Both SIGMA and FNXS can be transformed into water 
					saturation.
 
 On
                	very old logs, the primary derived value from the pulsed neutron
                device is the neutron decay time (TAU), for Schlumberger logs
                and the Neutron Half Life (LIFE) for Dresser logs. These are related
                to the formation capture cross section (SIGMA), by the following
                equation:
 1:
                SIGMA = 4550 / TAU for the Schlumberger tool
 2:
                SIGMA = 3150 / LIFE for the Dresser tool
 On
                modern logs, and many older ones, the SIGMA curve is displayed
                and the above calculation is not needed. 
					
			3: SIGMA= PHIe * Sw * SIGw (water term) Water Saturation from TDT log. Here is the log response equation for 
			the SIGMA measurement with only hydrocarbon and water in the porosity:
 + PHIe * (1 - Sw) * SIGh (hydrocarbon term)
 + Vsh * SIGsh (shale term)
 + (1 - Vsh - PHIe) * Sum (Vi * SIGi) (matrix 
			term)
 Where:
 SIGh = log reading in 100% hydrocarbon
 SIGi = log reading in 100% of the ith component of matrix rock
 SIGMA = log reading
 SIGsh = log reading in 100% shale
 SIGw = log reading in 100% water
 PHIe = effective porosity (fractional)
 Sw = water saturation in reservoir (fractional)
 Vi = volume of ith component of matrix rock
 Vsh = volume of shale (fractional)
 
 This equation is solved for Sw by assuming all other variables are 
			known or previously calculated:
 4:  SIGw = 22.0 + 0.000404 * WS(ppm)
 5: SIGm = Sum (Vi * SIGi)
 6: PHIe = TPHI from log if available
			and no gas OR from 
			open hole logs
 7: SWtdt = ((SIGMA - SIGm) - PHIe * (SIGh – SIGm) - Vsh * (SIGsh 
			- SIGm))
 / (PHIe * (SIGw - SIGh))
 
 Solving the fast neutron response equation with CO2 instead o 
			hydrocarbon gives:
 8: FNXSm, = Sum (Vi * FNXSi)
 9: SWfnxs = ((FNXS-FNXSm)-PHIe*(FNXSco2-FNXSm)-Vsh*(FNXSsh-FNXSm))
 / (PHIe * (FNXSw - FNXSco2))
 
 
 
  NUMERICAL
                EXAMPLE: 1. Assume data as follows:
 PHIe = 0.28
 SIGw = 84 cu
 SIGm = 10 cu
 SIGh = 22 cu
 SIGMA = 25.5 cu
 Vsh = 0.20
 SIGsh = 37 cu
 SWtdt = ((25.5 - 10) - 0.28 * (10 - 22) - 0.20 * (37 - 10)) /
                (0.28 * (84 - 22)) = 0.39
 2.
                If zone contained gas:SIGh = 9 cu
 SWtdt = ((25.5 - 10) - 0.28 * (10 - 9) - 0.20 * (37 - 10)) / (0.28
                * (84 - 9)) = 0.49
 
 
				 Porosity
				from TDT LOGS In
                the case of the dual detector devices, porosity from the TDT log 
				(TPHI or PHItdt) is calculated from the ratio of the near and far 
				count rate. This is the
                same approach that is used for the open hole compensated neutron 
				log (CNL). Like  the CNL, gas effects
                must be taken into account.
 
				
				
  Limits to use of OLDER tdt for saturation calculations The
				capture cross section is relatively inaccurate in low salinity,
				low porosity situations. The chart shown below is used to
				determine under what conditions the log can be used. The C/O
				curve on modern tools often helps locate hydrocarbon zones in
				fresher water situations.
 
				 Find useful range of TDT log here
 To
                overcome this inaccuracy problem, older logs were run in multiple
                passes and the SIGMA curves summed to reduce statistics. Typically,
                five runs were summed. More modern tools have better signal to
                noise ratio and do not need multiple passes. However, saturation
                may still be inaccurate when salinity is less than 50,000 ppm.
                Check with the service company for useful salinity / porosity
                ranges on current tools as specifications are constantly changing The
                current Schlumberger tool is called the Reservoir Saturation Tool
                (RST) and the term TDT may disappear as newer tools replace older
                ones. 
				
				 RECOMMENDED Parameters - 2015 LIST 
				
					| 
					
					Material | 
					
					Sigma 
					
					
					(c.u.) | 
					
					TPHI | 
					FNXS (1/m) |  
					| 
					
					Quartz | 
					
					4.55 | 
					
					–0.03 | 
					
					6.84 |  
					| 
					
					Calcite | 
					
					7.08 | 
					
					0.00 | 
					
					7.51 |  
					| 
					
					Dolomite | 
					
					4.70 | 
					
					0.03 | 
					
					8.51 |  
					| 
					
					Orthoclase | 
					
					15.82 | 
					
					–0.05 | 
					
					6.33 |  
					| 
					
					Albite | 
					
					7.65 | 
					
					–0.04 | 
					
					6.69 |  
					| 
					
					Anhydrite | 
					
					12.45 | 
					
					–0.03 | 
					
					7.14 |  
					| 
					
					Pyrite | 
					
					90.53 | 
					
					0.01 | 
					
					6.60 |  
					| 
					
					Bituminous Coal | 
					
					15.79 | 
					
					0.68 | 
					
					7.72 |  
					| 
					
					Dry 
					Illite | 
					
					20.79a | 
					
					0.22 | 
					
					8.06 |  
					| 
					
					Wet 
					Illite | 
					
					21.00 
					
					a | 
					
					0.34 | 
					
					8.02 |  
					| 
					
					Dry 
					Smectite | 
					
					14.36 
					
					a | 
					
					0.29 | 
					
					8.36 |  
					| 
					
					Wet 
					Smectite | 
					
					19.23 
					
					a | 
					
					0.68 | 
					
					8.60 |  
					| 
					
					Water | 
					
					22.20 | 
					
					1.00 | 
					
					7.80 |  
					| 
					
					Kerogen 
					(CH 1.3g/cm3) | 
					
					20.18 | 
					
					0.98 | 
					
					9.07 |  
					| 
					
					CH4
					
					
					(0.05 g/cm3) | 
					
					2.50 | 
					
					–0.05 | 
					
					0.67 |  
					| 
					
					CH4
					
					
					(0.15 g/cm3) | 
					
					7.50 | 
					
					0.21 | 
					
					2.01 |  
					| 
					
					CH4
					
					
					(0.25 g/cm3) | 
					
					12.50 | 
					
					0.47 | 
					
					3.36 |  
					| 
					
					Oil 
					(C3H8
					
					
					0.5g/cm3) | 
					
					18.21 | 
					
					0.78 | 
					
					5.44 |  
					| 
					
					Oil 
					(C3H8
					
					
					0.6g/cm3) | 
					
					21.85 | 
					
					0.97 | 
					
					6.53 |  
					| 
					
					Diesel 
					(CH1.8
					
					
					0.89 g/cm3) | 
					
					23.30 | 
					
					1.08 | 
					
					7.98 |  
					| 
					
					CO2
					
					
					(0.6 g/cm3) | 
					
					0.03 | 
					
					–0.12 | 
					
					2.24 |  
					| 
					
					Water 0 ppm | 
					
					22.2 | 
					
					1.00 | 
					
					7.800 |  
					| 
					
					Water 200,000 ppm | 
					
					97.2 | 
					
					0.90 | 
					
					7.36 |    
				
				 Parameters 
				- 1982 LIST 
				Some good legacy data 
			here from early sources.
 SIGMAwater (SIGW)
				is best derived from water salinity, which in turn can be
				derived from water resistivity:
 10: WS = 400000 / FT1 / ((RW@ET) ^ 1.14)
 11: 
				
				SIGw = 22.0 + 0.000404 * WS
 
 Where:
 BHT = bottom hole temperature (degrees Fahrenheit or Celsius)
 BHTDEP = depth at which BHT was measured (feet or meters)
 DEPTH = mid-point depth of reservoir (feet or meters)
 FT = formation temperature (degrees Fahrenheit or
				Celsius)
 FT1 = formation temperature (degrees Fahrenheit)
 RW@FT = water resistivity at formation temperatures (ohm-m)
 SUFT = surface temperature (degrees Fahrenheit or Celsius)
 WS = water salinity (ppm NcCl)
 SIGMA for hydrocarbon
					(SIGh)
					ranges between 0 and 23, with a default of 22 cu for typical
					oil and 9 cu for gas. See graphs below. 
				 SIGMA values for oil, gas, and water
 
 SIGMA values for shale
					(SIGsh) ranges between 20 and 45. You can look at a depth plot of
                your log, find the nearest, fairly thick, shale as observed on
                the gamma ray log and read the average of the SIGMA curve over
                the same interval. If GR is not a good shale indicator, try density
                neutron separation or shallow resistivity
 A
                crossplot of GR vs SIGMA will do the same thing (as long as radioactivity
                is a function of shale minerals and not uranium). Find the cluster
                of high GR values representing shale and pick the corresponding
                SIGMA shale. SIGMA for matrix rock (SIGm)
				can be taken from chartbook tables or can be calculated from the
				SIGMA log curve if porosity is known from conventional log
				analysis. The values in the chartbook
                tables do not work well because real rocks are not pure minerals.
                A method for finding SIGMAM from the log data itself uses the
                following equation:9. SIGm = (SIGMA - PHIe * SIGw) / (1 - PHIe)
 This
                eliminates the salt in the water in the porosity (SIGMA salt =
                770) and accounts for any other minerals in the sandstone (for
                example an iron rich cement where SIGMA iron = 220). Most real
                rocks have SIGMA larger than the values in the tables in chartbooks.
                You can vary SIGMA matrix point by point or take an average of
                several calculated values. Where:SIGm = capture cross section of matrix (capture units)
 SIGMA = capture cross section log reading (capture units)
 SIGw = capture cross section of water (capture units)
 PHIe = effective porosity (fractional)
 This
                should be done in a clean porous interval containing water. 
				 MATRIX PARAMETERS FOR PURE MINERALS Caution: these values are for pure minerals and values for real
                rocks are often higher.
 
                
                  | MINERAL | SIGm |  
                  | Quartz
                    SiO2 | 4.3 |  
                  | Calcite
                    CaCO3 | 7.3 |  
                  | Dolomite
                    CaCO3.MgCO3 | 4.8 |  
                  | Feldspars |  |  
                  | Albite
                    NaALSi3O8 | 7.6 |  
                  | Anorthite
                    CaALSi2O8 | 7.4 |  
                  | Orthoclase
                    KAlSi3O8 | 15.0 |  
                  | Evaporites |  |  
                  | Anhydrite
                    CaSO4 | 13.0 |  
                  | Gypsum
                    CaSO4.2H2O | 19.0 |  
                  | Halite
                    NaCl | 770 |  
                  | Sylvite
                    KCl | 580 |  
                  | Carnallite
                    KCl.MgCl2.6H2O | 370 |  
                  | Borax
                    Na2B4O7.10H2O | 9000 |  
                  | Kermite
                    Na2B4O7.4H2O | 10500 |  
                  | Coal |  |  
                  | Lignite | 30
                    +/-5 |  
                  | Bituminous
                    coal | 35
                    +/-| |  
                  | Anthracite | 22
                    +/-5 |  
                  | Iron-Bearing
                    Minerals |  |  
                  | Iron
                    Fe | 220 |  
                  | Geothite
                    FeO(OH) | 89.0 |  
                  | Hematite
                    Fe2O3 | 104 |  
                  | Magnetite
                    Fe3O4 | 107 |  
                  | Limonite
                    FeO(OH).3H2O | 80.0 |  
                  | Pyrite
                    FeS2 | 90.0 |  
                  | Siderite
                    FeCO3 | 52.0 |  
                  | Iron-Potassium
                    Bearing Minerals |  |  
                  | Glauconite
                    (green sands) | 25
                    +/-5 |  
                  | Chlorite | 25
                    +/-15 |  
                  | Mica
                    (Biotite) | 35
                    +/-1 |  
                  | Illite
                    Shale | 37
                    +/-5 |  
                  | Others |  |  
                  | Pyrolusite
                    MnO2 | 440 |  
                  | Manganite
                    MnO(OH) | 400 |  
                  | Cinnabar
                    HgS | 7800 |  
                  |  |  |